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メディア授業とは，メディアを利用して遠隔方式により実施する授業の授業時数が，総授業時数の半数を超える授業をいいます。
メディア授業により取得した単位は，卒業要件として修得すべき単位のうち60単位を超えないものとされています。
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This course is for students majoring chemistry, who have already studied the courses of Organic Chemistry I, II and III. The course covers Chapters 16-24 of the textbook dealing with the chemistry of carbonyl functionality, carboxylic acids and their derivatives, and reactions controlled by orbital symmetry. By completing a series of organic chemistry classes including this class, students can obtain comprehensive knowledge of basic organic chemistry at the university level.
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To learn reactions and structures of carbonyl compounds to obtain comprehensive knowledge of organic chemistry.
☑️To be able to understand the chemistry of carbonyl compounds as well as to be able to obtain comprehensive knowledge of organic chemistry.
☑️To be able to predict chemical properties and reactivities of organic molecules from carbonyl groups.
☑️To be able to judge the reactivity and physical properties of organic molecules from the character of functional groups, and To be able to systematize properties and reactivities of organic molecules by applying the fundamental theories of organic chemistry, and To be able to get a sense of organic chemistry.
☑️To be able to solve problems by making full use of the basic knowledge and data of organic chemistry.
☑️To be able to study independently and actively, and To be able to continuously obtain knowledge of organic chemistry.
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The course covers the chemistry of carbonyl functionality, carboxylic acids and their derivatives, and reactions controlled by orbital symmetry. The lecture will be provided with a projector. Quiz will be given at the beginning of the every lectures to encourage your study at home. In principle, the quiz will be came from the content of the out-of-class study instruction on the relevant lecture day. Attendance will be checked by submission of the quiz answer sheet.
As far as the number of students is within the capacity of the lecture room specified by the guidelines of Yamaguchi University, face-to-face classes will be held. Online classes may be held depending on the situation. The change will be announced by Shugaku-shien system (e-mail). If Yamaguchi University requests an online class on the day of the review exercise, the exercise will be considered as an exam and will be held in a face-to-face class.
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第1回
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Chap. 16 Carbonyl Chemistry 1: Addition Reactions
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hydrate, acetal, imine, etc.
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第2回
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Chap. 16 Carbonyl Chemistry 1: Addition Reactions
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alcohol synthesis, Wittig reaction, etc.
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第3回
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Chap.17 Carboxylic Acids
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preparations and transformations (ester, amide), etc.
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第4回
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Chap.17 Carboxylic Acids
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transromations (acid halide, acid anhydride), organometallic reagents, decarboxylation, etc.
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第5回
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Chap. 18 Derivatives of Carboxylic Acids: Acyl Compounds
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transformations, etc.
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第6回
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Chap. 18 Derivatives of Carboxylic Acids: Acyl Compounds
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rearrangements, etc.
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第7回
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mid-term review exercise
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review the lectures by problem-solving test
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第8回
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Chap. 19 Carbonyl Chemistry 2: Reaction at the alpha-position
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enol/enolate, racemization, halogenation, etc.
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第9回
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Chap. 19 Carbonyl Chemistry 2: Reaction at the alpha-position
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alkylation, aldol reaction, etc.
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第10回
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Chap. 19 Carbonyl Chemistry 2: Reaction at the alpha-position
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intra & cross aldol reaction, Claisen condensation, etc.
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第11回
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Chap. 19 Carbonyl Chemistry 2: Reaction at the alpha-position
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dithiane, Mannich reaction, Cannizzaro reaction, MPVO reaction, etc.
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第12回
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Chap. 23 Aromatic Transition State: Orbital Symmetry
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electrocyclic reaction, etc.
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第13回
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Chap. 23 Reactions Controlled by Orbital Symmetry
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sigmatropic shifts, Cope rearrangement, etc.
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第14回
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Chap. 24 Intramolecular Reactions and Neighboring Group Participation
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heteroatom, pai-electron, single bond, etc.
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第15回
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final review exercise
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review the lectures by problem-solving test
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※AL（アクティブ・ラーニング）欄に関する注
・授業全体で、AL（アクティブ・ラーニング）が占める時間の割合を、それぞれの項目ごとに示しています。
・A〜Dのアルファベットは、以下の学修形態を指しています。
【A：グループワーク】、【B：ディスカッション・ディベート】、【C：フィールドワーク（実験・実習、演習を含む）】、【D：プレゼンテーション】
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A: --% B: --% C: 10% D: --%
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Grading is based on the mid-term & final review exercises (80%) and quizzes (20%).
Attendance at the two review exercises is mandatory, and attendance for at least 80% of the lecture days (excluding the two review exercise days) is required.
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ジョーンズ有機化学 上・下（第5版）
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9784807908936
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Jr.,Maitland Jones (著), Steven A. Fleming (著), 奈良坂 紘一 (翻訳), 山本
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東京化学同人
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2016
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備考
Same as Organic Chemistry I~III courses, "Jones Organic Chemistry (5th edition)" is used as a textbook. The lecture will be provided with a projector.
Most of the lecture materials and the quiz are came from the textbook.
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ウォーレン有機化学 上・下（第2版）
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9784807908714
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Jonathan Clayden (著), Stuart Warren (著), Nick Greeves (著), 野依 良
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東京化学同人
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2015
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基礎講座 有機化学
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4759820566
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松島芳隆, 渡邊総一郎, 古荘義雄著
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化学同人
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2022
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備考
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Please find any textbooks that suits yourself to study, since many books relating to organic chemistry are collected in the library.
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Studying before and reviewing after lectures are effective for deep understanding of the textbook. The students are highly recommended to read the textbook in advance of each lecture. Please work on the problems in the text by your own to organize knowledge as well as to get a sense of organic chemistry. Organic chemistry is tend to require you to of build-up knowledge. Students, who feel this lecture is too hard, are recommended to re-study the relevant parts of Organic Chemistry I~III before attending the lecture. In addition, a quiz will be given at the beginning of the every lectures to encourage your study at home.
I would like to introduce the common contents in modern organic chemistry as much as possible, although none of them are shown in the basic organic chemistry textbook (Jones Organic Chemistry). For those information, please refer to the books in the reference section.
Students, who do not aim to obtain credits, are also welcome to attend the class.
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organic chemistry, carbonyl compounds
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| (教育)すべての人に包摂的かつ公正な質の高い教育を確保し、生涯学習の機会を促進する。 |
| (エネルギー)すべての人々の、安価かつ信頼できる持続可能な近代的エネルギーへのアクセスを確保する。 |
| (持続可能な生産と消費)持続可能な生産消費形態を確保する。 |
| (気候変動)気候変動及びその影響を軽減するための緊急対策を講じる。 |
| (海洋資源)持続可能な開発のために海洋・海洋資源を保全し、持続可能な形で利用する。 |
| (陸上資源)陸域生態系の保護、回復、持続可能な利用の推進、持続可能な森林の経営、砂漠化への対処、ならびに土地の劣化の阻止・回復及び生物多様性の損失を阻止する。 |
| (実施手段)持続可能な開発のための実施手段を強化し、グローバル・パートナーシップを活性化する。 |
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Organic Chemistry I, II, III
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Registration is recommended for those who have taken Organic Chemistry I, II, and III.
Students, who do not aim to obtain credits, are also welcome to attend the class.
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Please ask me after class when you have a question.
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