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メディア授業とは，メディアを利用して遠隔方式により実施する授業の授業時数が，総授業時数の半数を超える授業をいいます。
メディア授業により取得した単位は，卒業要件として修得すべき単位のうち60単位を超えないものとされています。
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In addition to the concepts of energy (internal energy, enthalpy, and entropy) learned in Physical Chemistry I, this course newly introduces the concept of free energy, which forms the core of thermodynamics. Students will develop a fundamental understanding of equilibrium in pure substances (single-component systems), multicomponent systems, and chemical equilibria involving reactions. The course examines what governs equilibrium and where the fundamental principles underlying its nature reside.
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・Understand and explain the concept of free energy.
・Describe state changes and chemical reactions from the viewpoint of free energy.
・Understand the meaning of chemical equilibrium in thermodynamics and explain chemical phenomena from the perspective of equilibrium theory.
・Visualize and describe reactions and phenomena treated in other chemistry courses from a thermodynamic perspective.
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Lectures will be given on the topics listed below. At the beginning of each class, approximately 20 minutes will be devoted to explanations of exercise problems. In addition, the final 20–30 minutes of each class will be used for review or practice problems related to that day’s lecture.
Announcements regarding the course and submission of assignments will be handled through the learning support system.
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第1回
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Introduction
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Review of Physical Chemistry I; concept of chemical equilibrium
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第2回
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Free energy
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Concepts of Helmholtz free energy and Gibbs free energy
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第3回
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Fundamental thermodynamic equations and Maxwell relations
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How Maxwell relations are formulated; derivation of thermodynamic equations of state
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第4回
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Properties of the Gibbs free energy
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Temperature and pressure dependences of the Gibbs free energy
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第5回
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Chemical potential
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Concept of chemical potential and its relation to free energy
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第6回
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Phase equilibrium
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Phase equilibrium and chemical potential in pure substances (single-component systems)
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第7回
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Phase equilibrium
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Clapeyron–Clausius equation; temperature and pressure dependence of phase equilibrium
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第8回
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Interim summary
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Exercises
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第9回
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Thermodynamics of mixing
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Concept of partial molar quantities
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第10回
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Properties of solutions
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Ideal solutions: Raoult's law and Henry's law
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第11回
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Properties of solutions
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Colligative properties of solutions
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第12回
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Chemical equilibrium
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Chemical reactions and Gibbs free energy
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第13回
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Chemical equilibrium
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Equilibrium constants and chemical equilibrium
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第14回
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Chemical equilibrium and reaction kinetics
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Bridge to the required second-semester course “Reaction Kinetics”
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第15回
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Overall summary
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Final examination
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※AL（アクティブ・ラーニング）欄に関する注
・授業全体で、AL（アクティブ・ラーニング）が占める時間の割合を、それぞれの項目ごとに示しています。
・A〜Dのアルファベットは、以下の学修形態を指しています。
【A：グループワーク】、【B：ディスカッション・ディベート】、【C：フィールドワーク（実験・実習、演習を含む）】、【D：プレゼンテーション】
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A: --% B: 5% C: 10% D: --%
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In principle, evaluation will be based on the results of the Final examination.
Final examination: 95%; in-class assignments, reports, and others: 5%.
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アトキンス物理化学(上)
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9784807906956
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Peter Atkins, Julio de Paula著 ; 千原秀昭, 中村亘男訳
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東京化学同人
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2009
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備考
Classes will generally follow the textbook. Since many of the exercises will be based on problems from the textbook, students are required to purchase it.
Because calculation problems will be worked on during the exercises, students should bring a scientific calculator.
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備考
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Many reference books and textbooks on physical chemistry are available. They are available in the library, so please consult them and use those that best support your understanding (purchase them if necessary).
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The content of physical chemistry covers fundamental principles common to all areas of chemistry. Even if you do not understand everything immediately, repeated study will help deepen your understanding. Rather than memorizing equations indiscriminately, focus on understanding the underlying concepts.
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Thermodynamics, equilibrium, and free energy
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| (エネルギー)すべての人々の、安価かつ信頼できる持続可能な近代的エネルギーへのアクセスを確保する。 |
| (持続可能な生産と消費)持続可能な生産消費形態を確保する。 |
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Physical Chemistry I, Reaction Kinetics, Analytical Chemistry
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e-mail: k-fujii(at)yamaguchi-u.ac.jp (at = @)
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Every Wednesday, 10:30–12:00
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