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メディア授業とは，メディアを利用して遠隔方式により実施する授業の授業時数が，総授業時数の半数を超える授業をいいます。
メディア授業により取得した単位は，卒業要件として修得すべき単位のうち60単位を超えないものとされています。
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For a systematic study of organic chemistry, this course covers hydroxy functional groups: alcohols, alcohol reactions and ether chemistry, alkene reactions, alkynes, delocalized π-electron systems, benzene and aromaticity, and electrophilic attacks on benzene derivatives.
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Understand their properties with respect to organic reactions.
To be able to distinguish between electrophiles and nucleophiles.
To be able to describe the reaction mechanism and understand the reaction.
Understand the difference in reactivity of each functional group in complex compounds and write appropriate reaction mechanisms.
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For a systematic study of organic chemistry, this course covers hydroxy functional groups: alcohols, alcohol reactions and ether chemistry, alkene reactions, alkynes, delocalized π-electron systems, benzene and aromaticity, and electrophilic attacks on benzene derivatives.
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第1回
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Chapter 8.
Hydroxy group
Alcohol (1)
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Naming the alcohols
Oxidation-Reduction of carbonyl compounds of alcohols
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第2回
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Chapter 8. Nucleophilic addition to carbonyl group in aldehydes and ketones (2)
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Synthesis of Alcohols and Organometallic Reagents
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第3回
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Chapter 9.
Reactions of Alcohols and Chemistry of Ethers (1)
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Reactions of Alkoxides
Reactions of alcohols with strong acids
Carbocation rearrangement
Synthesis of esters and haloalkanes from alcohols
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第4回
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Chapter 9.
Reactions of Alcohols and Chemistry of Ethers (2)
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synthesis of ether
Reactivity of Ethers
Oxacyclopropanation reaction
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第5回
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Chapter 12.
Reactions of alkenes (1)
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Addition reaction of alkenes
Hydrogenation reactions
Hydration Reactions
Electrophilic Addition Reactions
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第6回
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Chapter 12.
Reactions of alkenes (2)
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Oxymercurcation - Demercurcation
Hydroboration reaction
Synthesis of cyclopropanes
Epoxide Synthesis
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第7回
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Chapter 12.
Reactions of alkenes (3)
Chapter 13.
Reactions of alkynes (1)
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Dihydroxylation reaction
Ozonolysis
Radical addition reaction
Dimerization, polymerization
Alkyne naming
Alkynyl anions
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第8回
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Chapter 13.
Reactions of alkynes (2)
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Reduction
Anti-Markovnikov addition reaction
Alkenyl halide
Transition metal-catalyzed reaction
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第9回
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midterm exercises
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All contents from the 1st to the 8th session
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第10回
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Chapter 14.
Delocalized pi-electron systems (1)
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Allyl radicals, anions, and cations
Substitution reaction at the allyl position
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第11回
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Chapter 14.
Delocalized pi-electron systems (2)
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Transformation of conjugated dienes
Electrocyclic Reactions
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第12回
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Chapter 15.
Benzene and Aromaticity (1)
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Benzene
Resonance Energy of benzene
π-molecule activation
Polycyclic aromatic hydrocarbons
Huckel's rule
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第13回
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Chapter 15.
Benzene and Aromaticity (2)
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Electrophilic substitution reaction (1)
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第14回
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Chapter 16.
Electrophilic attack on derivatives of benzene (1)
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Electrophilic substitution reaction (2)
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第15回
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Chapter 16.
Electrophilic attack on derivatives of benzene (2)
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Electrophilic substitution reaction (3)
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第16回
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Final exam
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All parts of chapters so far studied
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※AL（アクティブ・ラーニング）欄に関する注
・授業全体で、AL（アクティブ・ラーニング）が占める時間の割合を、それぞれの項目ごとに示しています。
・A〜Dのアルファベットは、以下の学修形態を指しています。
【A：グループワーク】、【B：ディスカッション・ディベート】、【C：フィールドワーク（実験・実習、演習を含む）】、【D：プレゼンテーション】
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A: --% B: --% C: 10% D: --%
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Evaluation will be based on quizzes and a written test at the end of the semester.
(Quiz: 5%, written test at the end of the semester: 95%)
If attendance is less than 70%, the student will be disqualified.
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ボルハルト・ショアー現代有機化学
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9784759820294
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K.P.C. Vollhardt, N.E. Schore [著] ; 大嶌幸一郎 [ほか] 訳
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化学同人
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2019
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ボルハルト・ショアー現代有機化学
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9784759820300
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K.P.C. Vollhardt, N.E. Schore [著] ; 大嶌幸一郎 [ほか] 訳
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化学同人
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2020
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備考
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Organic chemistry is an important part of “material production,” which occupies an important position in chemistry. It is an essential field of study for chemistry specialists, so please study it carefully.
In understanding organic chemistry, it is essential to distinguish between nucleophiles and electrophiles. To understand this, the periodic table is very important.
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Alcohol, alkene, alkyne, benzene, electrophilic substitution reaction
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| (教育)すべての人に包摂的かつ公正な質の高い教育を確保し、生涯学習の機会を促進する。 |
| (水・衛生)すべての人々の水と衛生の利用可能性と持続可能な管理を確保する。 |
| (エネルギー)すべての人々の、安価かつ信頼できる持続可能な近代的エネルギーへのアクセスを確保する。 |
| (持続可能な生産と消費)持続可能な生産消費形態を確保する。 |
| (陸上資源)陸域生態系の保護、回復、持続可能な利用の推進、持続可能な森林の経営、砂漠化への対処、ならびに土地の劣化の阻止・回復及び生物多様性の損失を阻止する。 |
| (実施手段)持続可能な開発のための実施手段を強化し、グローバル・パートナーシップを活性化する。 |
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Chemistry II (common basic course for freshmen), Organic Chemistry II (second year)
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tak102★yamaguchi-u.ac.jp
（★は@に置き換えてください。）
総合研究棟711
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I will accept students anytime during class days (from 9:00 a.m. to 5:00 p.m., excluding holidays and substitute holidays, but excluding times when I am away on business or teaching in Yamaguchi) during the semester until the end of the examinations. However, please make an appointment in advance by e-mail.
If you have any questions or comments, please send them from the university address.
Emails from personal private addresses will be classified as junk mail.
Also, please understand the minimum rules of e-mail before sending.
Translated with www.DeepL.com/Translator (free version)
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