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メディア授業とは，メディアを利用して遠隔方式により実施する授業の授業時数が，総授業時数の半数を超える授業をいいます。
メディア授業により取得した単位は，卒業要件として修得すべき単位のうち60単位を超えないものとされています。
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There are so many organic reactions including base, or acid mediated reactions, rearrangements, concerted reactions and so on. In this lecture, I will lecure on metal-caltalyzed organic reactions, such as cross-couplings, and asymmetric hydrogenations.
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Acquisition of knowledge necessary for synthesis.
Understanding of catalytic reactions. To be able to select appropriate reactions for synthesis.
Understand the principles of reactions. To be interested in how synthetic reactions have been developed and how much impact they have had on society.
How to understand how synthetic reactions have been developed and how much impact they have had on society, and how they can be applied to the future of organic chemistry.
To be able to acquire the knowledge of organic chemistry as a future leader in the field of organic chemistry.
To actively develop an interest in many synthetic reactions. To enable students to use their knowledge of synthesis accurately.
To improve overall skills in organic synthesis through exercises.
To be able to prepare and submit assignments (reports) by the due date.
Translated with DeepL.com (free version)
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THe first goal is understanding the metal complexes and their basic reactivities. The second is understanding a catalytic cycle. The final goal is understanding metal-catalyzed organic reactions.
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第2回
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bonding and oxidation number
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metal complex
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第3回
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the basic of catalytic cycle
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the reactivities of metal complex
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第4回
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organometallic compounds
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magnesium lithium, zinc, boron and silicon compounds
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第5回
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asymmetric hydrogenation and ligands
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chiral ligands and metal complex for hydrogenation and related reactions
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第6回
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cross-coupling 1
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historical background
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第7回
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cross-coupling 2
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applications
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第8回
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1,4-additions
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the basic theory and applications
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第9回
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allylations
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the basic theory and applications
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第10回
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oxidations and reductions
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the basic theory and applications
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第11回
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metallations
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C-M bond formations
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第12回
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Miscellaneous reactions
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the role of the catalyst
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第13回
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inert bond activations
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C-H activations
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第14回
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elemental strategy
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the future of catalytic reactions
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※AL（アクティブ・ラーニング）欄に関する注
・授業全体で、AL（アクティブ・ラーニング）が占める時間の割合を、それぞれの項目ごとに示しています。
・A〜Dのアルファベットは、以下の学修形態を指しています。
【A：グループワーク】、【B：ディスカッション・ディベート】、【C：フィールドワーク（実験・実習、演習を含む）】、【D：プレゼンテーション】
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A: --% B: --% C: --% D: --%
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Attendance, in-class reports, and written tests will be evaluated.
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備考
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村井眞二訳、ヘゲダス遷移金属触媒による有機合成、東京化学同人
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有機金属や触媒反応の取り扱いについて学んでもらいます
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Organic synthesis, organometallics
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| (持続可能な生産と消費)持続可能な生産消費形態を確保する。 |
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