山口大学教務システム - 1061330910-配位化学

開講年度	開講学部等
2025	工学部
開講学期	曜日時限	授業形態	AL（アクティブ・ラーニング）ポイント
前期	火5～6	講義
時間割番号	科目名[英文名]			使用言語	単位数
1061330910	配位化学[Coordination Chemistry]			日本語	2
担当教員（責任）[ローマ字表記]					メディア授業
中山雅晴[NAKAYAMA Masaharu]					ー
担当教員[ローマ字表記]
中山雅晴　[NAKAYAMA Masaharu]
特定科目区分		対象学生		対象年次	3～
ディプロマ・ポリシーに関わる項目			カリキュラムマップ(授業科目とDPとの対応関係はこちらから閲覧できます)

授業の目的と概要

Coordination Chemistry began with "Coordination Theory" proposed by Werner in 1905, which now covers non-Werner-type complexes such as organic metal compounds. You will know the birth of Coordination Chemistry and the following development. You are expected to master the nomenclature of Werner- and non-Werner-type complexes, symmetry, reactivity, and isomerism. You are required to understand crystal field theory and ligand field theory as a basis of transition elements and to know properties of the compounds.This class will be made by a faculty member who has practical experience in the research and development department of a chemical manufacturer, and the lecture includes more practical ideas.

授業の到達目標

・You will be able to understand the symmetry and isomerism of complexes.
・You will be able to explain the stability, magnetic properties and electronic spectra of complexes based on crystal field theory and ligand field theory.
・You will be able to explain the characteristics of metal-π-acidic ligand complexes.
・Coordination compounds are made up of metal ions and ligands (inorganic molecules and organic compounds), and there are many of them in the human body and around us, and you will be able to point out their functions.
・You can discuss the role of metal complexes in modern technology from the perspective of coordination chemistry.

授業計画

【全体】

At first, you will know from the birth of Coordination Chemistry to the historical background. Then, nomenclature of complexes, symmetry, isomerism, ligand field theory, and transition metals will be mastered. Several short tests will be taken to confirm your understanding.

	項目	内容	授業時間外学習	備考

第1回	1. Introduction and historical development	(1)Werener's coordination theory, (2)Kinds of ligands, (3)Coordination number, (4)Nomenclature	4th ed, p.331〜348 Preparation and review (approx. 4 hours or more of study time)

第2回

2. Coordination bonding

(1)Coupling of electron spins, (2)Electronic structure of atom, (3)Valence bond theory

Preparation and review (approx. 4 hours or more of study time)

第3回

3. Symmetry of complexes

(1)Rotation axis, (2)Symmetric plane, (3)Symmetric plane, (4)Rotatory reflection

4th ed., p.296〜300
Preparation and review (approx. 4 hours or more of study time)

第4回

4. Stereochemistry of complexes

(1)Geometric isomerism, (2)Optical isomerism, (3) Other isomerism

4th ed., p.348〜360
Preparation and review (approx. 4 hours or more of study time)

第5回

5. Reactions of coordination chemistry I

(1)Thermodynamic consideration, (2)Ligand exchange rate, (3)Classification of reaction mechanisms

4th ed., p.753〜803(mainly in the first half)
Preparation and review (approx. 4 hours or more of study time)

第6回

6. Reactions of coordination chemistry II

(1)Nucleophilicity of entering group，(2)Isomerization reactions, (3)Redox reactions

4th ed., p.753〜803(mainly in the second half)
Preparation and review (approx. 4 hours or more of study time)

第7回

7. Stability of complexes

(1)Stability constants of complexes, (2)Chelating effect

4th ed., p.754〜758
Preparation and review (approx. 4 hours or more of study time)

第8回

8. Reaction kinetics of coordination compounds I

(1)Reaction rate equation, (2)Mechanisms of substitution reactions

4th ed., p.759〜766
Preparation and review (approx. 4 hours or more of study time)

第9回

Practices

The contents from 1st to 8th weeks will be practiced.

Additional Information
Preparation and review (approx. 4 hours or more of study time)

第10回

9. Reaction kinetics of coordination compounds II

(1)Reaction rate equation, (2)Mechanisms of substitution reactions

4th ed., p.759〜766
Preparation and review (approx. 4 hours or more of study time)

第11回

10. Coordination bonding I

(1)Valence bond theory，(2)Crystal field theory

4th ed., p68〜p75，p704〜724
Preparation and review (approx. 4 hours or more of study time)

第12回

11. Coordination bonding II

Jahn-Teller effect

4th ed., p.715-717
Preparation and review (approx. 4 hours or more of study time)

第13回

12. Ligand-field theory I

Ligand-field theory I

4th ed., p.717〜724
Preparation and review (approx. 4 hours or more of study time)

第14回

13. Ligand-field theory II

Ligand-field theory II

4th ed, p.717〜724
Preparation and review (approx. 4 hours or more of study time)

第15回

14. Organometallic Chemistry

Organometallic compounds

4th ed., p.814〜817
Preparation and review (approx. 4 hours or more of study time)

第16回

End-term examination

Written examination

Additional Information
Preparation and review (approx. 4 hours or more of study time)

※AL（アクティブ・ラーニング）欄に関する注
・授業全体で、AL（アクティブ・ラーニング）が占める時間の割合を、それぞれの項目ごとに示しています。
・A〜Dのアルファベットは、以下の学修形態を指しています。
【A：グループワーク】、【B：ディスカッション・ディベート】、【C：フィールドワーク（実験・実習、演習を含む）】、【D：プレゼンテーション】

A: --%　B: --%　C: --%　D: --%

成績評価法

Attendance 5%, Homework 5%, End-of-term written test 90%

教科書にかかわる情報

教科書	書名	シュライバーアトキンス無機化学				ISBN	9784807906673
教科書	著者名		出版社	東京化学同人				出版年	2008

備考

参考書にかかわる情報

参考書	書名	無機化学概論				ISBN	9784621082881
参考書	著者名	小倉興太郎	出版社	丸善				出版年	2001

備考

メッセージ

(1)You are expected to understand the concepts of Coordination Chemistry and pay attention to its location in Chemistry and the relationship with other subjects.
(2)You will automatically fail if you attend less than 60% of the classes.

キーワード

Coordination, Werner-type complex, Nomenclature, Ligand field theory, Transition element, Teacher with practical experience

持続可能な開発目標（SDGs）

(エネルギー)すべての人々の、安価かつ信頼できる持続可能な近代的エネルギーへのアクセスを確保する。

(持続可能な生産と消費)持続可能な生産消費形態を確保する。

(気候変動)気候変動及びその影響を軽減するための緊急対策を講じる。

メディア授業