山口大学教務システム - 1062320760-高分子化学Ⅰ

開講年度	開講学部等
2025	工学部
開講学期	曜日時限	授業形態	AL（アクティブ・ラーニング）ポイント
後期	月3～4	講義	0.5
時間割番号	科目名[英文名]			使用言語	単位数
1062320760	高分子化学Ⅰ[Polymer ChemistryⅠ]			日本語	2
担当教員（責任）[ローマ字表記]					メディア授業
鬼村謙二郎[ONIMURA Kenjiro]					ー
担当教員[ローマ字表記]
鬼村謙二郎　[ONIMURA Kenjiro]
特定科目区分		対象学生		対象年次	2～
ディプロマ・ポリシーに関わる項目			カリキュラムマップ(授業科目とDPとの対応関係はこちらから閲覧できます)

授業の目的と概要

In the first half of this lecture, basic concepts of polymers, history, properties, and molecular weight will be provided, and students will learn basic knowledge of polymer synthesis. In addition, sequential reactions and chain polymerization of polymer synthesis are studied.

In the latter half of the course, students will learn about living polymerization methods and characteristics, stereochemistry of polymers, polymers showing special structures, and polymer reactions.

In addition, the importance of basic knowledge in the field of organic chemistry and polymer chemistry will be explained by drawing on practical experience in companies and research laboratories.
(Department of Applied Chemistry DP2, 3)

授業の到達目標

To be able to explain the difference between high-molecular-weight compounds and low-molecular-weight organic compounds.
To be able to explain chain polymerization and sequential polymerization.
To be able to explain polymerization methods and reaction mechanisms according to monomer structures.
To be able to discuss about polymer materials. Attendance is mandatory. To submit reports and other homework assignments without fail.

授業計画

【全体】

In this lecture, according to textbooks, and explain using slides in particular.
Explain the supplementary explanation using slides.
Solve the polymer chemistry problem and submit it as a report.

References and homework will be provided in "Moodle" and "Study Support System".

	項目	内容	授業時間外学習	備考

第1回	Chapter 1 Concept of polymer science	Concept of polymer History, structure, and properties of polymer Synthetic organic polymer	You are expected to have read Chapter 1 of the textbook before the class starts. (Standard study time: 4 hours or more)

第2回

Chapter 2
Structure of polymer

Explain the following:
Molecular weight and molecular weight distribution
Head-to-tail, head-to-head bond of polymer synthesis
Stereoregularity (tacticity)
Structure of polymer
Homopolymer and copolymer
Special structural polymer

You are expected to have read Chapter 2 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第3回

Chapter 3
Method of polymer synthesis

Explain the following:
Classification of polymerization reaction
Step-growth polymerization
Chain-growth polymerization
Living polymerization

You are expected to have read Chapter 3 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第4回

Chapter 4
Condensation polymerization

Explain condensation polymerization:
Characteristics, methods, and the mechanism of condensation polymerization.

You are expected to have read Chapter 4 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第5回

Chapter 4
Polyaddtion and Addtion-condensation

Explain the polyaddtion (synthesis and properties of polyurethane and its network polymer)
Explain the addtion-condensaion and phenolic resin

You are expected to have read Chapter 4 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第6回

Chapter 5
Radical polymerization (1)

Explain radical polymerization:
Elementary reaction
Kinetics
Methods

You are expected to have read Chapter 5 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第7回

Chapter 5
Radical polymerization (2)

Explain radical polymerization:
Copolymerization
Monomer reactivity ratio
Copolymer composition
Q-e theory

You are expected to have read Chapter 5 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第8回

Mid-term exam

Mid-term exam for confirming the level of understanding

Review Chapters 1-5.
(Standard study time: 4 hours or more)

第9回

Chapter 6
Ionic polymerization (1)

Explain anionic polymerization:
Characteristics of anionic polymerization
Living anionic polymerization

You are expected to have read Chapter 6 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第10回

Chapter 6
Ionic polymerization (2)

Explain cationic polymerization and living cationic polymerization

You are expected to have read Chapter 6 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第11回

Chapter 7
Coordination polymerization

Explain coordination polymerization.
Characterization of coordination polymerization
Stereoregular polymerization
Ziegler-Natta catalyst
Metallocene catalyst
Metathesis polymerization

You are expected to have read Chapter 7 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第12回

Chapter 7
Ring-opening polymerization

Explain ring-opening polymerization of cyclic monomers:
Characteristic of ring opening polymerization
Cationic ring-opening polymerization
Anion ring opening polymerization
Radical ring opening polymerization

You are expected to have read Chapter 7 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第13回

Chapter 8
Polymer reaction

Explain polymer reaction and example using polymer reaction:
Example using polymer reaction
Polymer gel
Polymer catalyst

You are expected to have read Chapter 8 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第14回

Chapter 9
Synthesis and decomposition of polymers by enzymes and microorganisms

Explain the following:
Polymer synthesis by enzymes / microorganisms
Enzyme catalyzed polymerization
Natural polymer
Biodegradable polymer

You are expected to have read Chapter 8 of the textbook before the class starts.
(Standard study time: 4 hours or more)

第15回

Practice for polymer chemistry

Total review from 1 to 14 weeks

Review Chapters 1-9.
(Standard study time: 4 hours or more)

第16回

Summary & Final exam

Understand all through examination

Review Chapters 1-9.
(Standard study time: 4 hours or more)

※AL（アクティブ・ラーニング）欄に関する注
・授業全体で、AL（アクティブ・ラーニング）が占める時間の割合を、それぞれの項目ごとに示しています。
・A〜Dのアルファベットは、以下の学修形態を指しています。
【A：グループワーク】、【B：ディスカッション・ディベート】、【C：フィールドワーク（実験・実習、演習を含む）】、【D：プレゼンテーション】

A: --%　B: --%　C: 5%　D: --%

成績評価法

Evaluation will be based on mid-term and final examinations, homework assignments, and out-of-class reports.
Routine examinations (mid-term and final): 80%
Homework and reports outside of class: 20%.

教科書にかかわる情報

教科書	書名	高分子化学化学の指針シリーズ				ISBN	9784785332273
教科書	著者名	西　敏夫，讃井浩平，東　千秋，高田十志和	出版社	裳華房				出版年	2016

備考

参考書にかかわる情報

備考

メッセージ

We will practice problems and interpretation for confirming the level of understanding at Seminar for Applied Chemistry IV.

キーワード

Condensation polymerization, Polyaddtion and Addtion-condensation, Radical polymerization, Anionic polymerization, ationic polymerization, Living polymerization, Coordination polymerization

持続可能な開発目標（SDGs）

(エネルギー)すべての人々の、安価かつ信頼できる持続可能な近代的エネルギーへのアクセスを確保する。

(持続可能な生産と消費)持続可能な生産消費形態を確保する。

(海洋資源)持続可能な開発のために海洋・海洋資源を保全し、持続可能な形で利用する。

メディア授業